Topical fungicides are best for prevention and don't work well for cure. The best you can do is start a preventive spray program when the weather is wet and humid and to keep sanitizing the plants removing fallen and infested leaves. You may have to pull heavily infested plants to prevent spread of the disease. Provide good air circulation and if you have problems try changing the location, spores will persist in the soil for a while. Solarize at the height of summer July-August.
Systemic fungicides do a better job on ornamentals like roses.
Copper sulfate is on the NOP list for allowed substances. Unless the product contains other things which are not allowed, it should be organic.
The bonide brand of copper sulfate should be organic
https://extension.umd.edu/learn/two-org ... -gardeners
§ 205.601 Synthetic substances allowed for use in organic crop production.
(I) As plant disease control.
(1) Aqueous potassium silicate (CAS #-1312-76-1) - the silica, used in the manufacture of potassium silicate, must be sourced from naturally occurring sand.
(2) Coppers, fixed - copper hydroxide, copper oxide, copper oxychloride, includes products exempted from EPA tolerance, Provided, That, copper-based materials must be used in a manner that minimizes accumulation in the soil and shall not be used as herbicides.
(3) Copper sulfate - Substance must be used in a manner that minimizes accumulation of copper in the soil.
(4) Hydrated lime.
(5) Hydrogen peroxide.
(6) Lime sulfur.
(7) Oils, horticultural, narrow range oils as dormant, suffocating, and summer oils.
https://www.law.cornell.edu/cfr/text/7/205.601